粉末粒度对储氢电极电化学性能的影响

以M1（NiCoMnTi）5为例,系统研究了粉末粒度对储氢电极电化学性能的影响。结果表明,在试验粒度范围内,合金粉越细,其放电容量越高,高倍率放电性能和循环稳定性也越好;将两种不同粒度的合金粉混合使用时,粒径相差越大,其放电容量越高。且当粗细粉质量比为7：3时,放电容量最高。     

复合材料单面胶接修复含中心裂纹铝合金板的疲劳特性分析

利用ANSYS有限元分析软件,建立了复合材料单面胶接修复铝合金裂纹板的裂纹长度参数化的有限元模型,分析了修复结构的裂纹尖端应力强度因子及其变化幅值的规律;与试验测试结果相结合,得到了描述修复结构疲劳特性的Paris公式材料常数;碳纤维、玻璃纤维复合材料胶接修复铝合金裂纹板的材料常数C、m分别为6.76×10-10、2.27和7.89×10-10、2.33。     

高速电弧喷涂耐磨涂层性能研究

将低碳马氏体和3Cr13+AlRE伪合金高速电弧喷涂层进行了性能和组织结构的对比分析。实验结果表明,与伪合金涂层相比,低碳马氏体涂层呈现出更优异的力学性能、耐磨性能和机械加工性能。该涂层可用于发动机曲轴等零件的再制造。     

水下制氢反应室动态过程数值分析

为研究水下制氢反应室的动态过程规律,基于化学反应动力学和单液滴运动学得到合金/水反应转化率,并在最小自由能法计算得到生成物各组分摩尔数的基础上利用质量守恒方程得到室内各物质质量变化规律。在建立非线性移动边界螺旋管动态模型的前提下,利用能量守恒方程得到室内热力参数变化规律,进而完成制氢反应室动态过程详尽模型的建立。利用该模型编写计算程序,完成某水下制氢反应室动态过程仿真。结果表明,各仿真曲线较好地反映了对应参数的动态变化规律,验证了模型建立与仿真的正确性;合金/水反应转化率决定了反应室的物质质量变化规律及其能量释放特性。该模型可以作为制氢反应室动态特性分析及其过程控制研究的基础模型。     

Fabrication of AA7005/TiB2-B4C surface composite by friction stir processing: Evaluation of ballistic behaviour

The present work aims to enhance the ballistic resistance of AA7005 alloy by incorporating the TiB₂ and B₄C ceramic reinforcement particles. Surface composites with different weight fractions of TiB₂ and B₄C particles were processed by friction stir processing. Micro-hardness and depth of penetration tests were carried out to evaluate the ballistic properties of the surface composites. The surface hardness of the composite was found to be nearly 70 HV higher than base alloy. The depth of penetration of the steel projectile was 20–26 mm in the composites as compared to 37 mm in the base alloy. Ballistic mass efficiency factor of the surface composite was found to be 1.6 times higher than base alloy. This is mainly attributed to the dispersion strengthening from the reinforcement particles.     

镁合金表面电弧喷涂Fe基非晶纳米晶涂层的性能

采用自动化高速电弧喷涂技术在镁合金基体上制备了FeCrBSiMoNbW非晶纳米晶涂层。采用Flir A20M型红外热像仪对Fe基非晶纳米晶喷涂层的表面温度场进行了实时监测。对Fe基非晶纳米晶涂层和传统的3Cr13涂层的组织结构、力学性能以及摩擦学性能进行了对比分析。实验结果表明：Fe基非晶纳米晶涂层组织致密,孔隙率低,具有相对较高的硬度和拉伸结合强度;形成了非晶相和纳米晶相组成的复合结构,使得涂层具备较好的耐磨减摩性能。     

Study of high-speed-impact-induced conoidal fracture of Ti alloy layer in composite armor plate composed of Ti-and Al-alloy layers

In order to understand the mechanism of conoidal fracture damage caused by a high-speed fragment-simulating projectile in titanium alloy layer of a composite armor plate composed of titanium- and aluminum-alloy layers, the ballistic interaction process was successfully simulated based on the Tuler-Butcher and GISSMO coupling failure model. The simulated conoidal fracture morphology was in good agreement with the three-dimensional industrial-computed-tomography image. Further, three main damage zones (zones I, II, and III) were identified besides the crater area, which are located respectively near the crater area, at the back of the target plate, and directly below the crater area. Under the high-speed-impact conditions, in zone II, cracks began to form at the end of the period of crack formation in zone I, but crack formation in zone III started before the end of crack formation in zone II. Further, the damage mechanism differed for different stress states. The microcracks in zone I were formed both by void connection and shear deformation. In the formation of zone I, the stress triaxiality ranged from-2.0 to-1.0, and the shear failure mechanism played a dominant role. The microcracks in zone II showed the combined features of shear deformation and void connection, and during the for-mation process, the stress triaxiality was between 0 and 0.5 with a mixed failure mode. Further, the microcracks in zone III showed obvious characteristics of void connection caused by local melting. During the zone III formation, the triaxiality was 1.0-1.9, and the ductile fracture mechanism was dominant, which also reflects the phenomenon of spallation.     

Numerical simulation study on penetration performance of depleted Uranium (DU) alloy fragments

Due to its high strength, high density, high hardness and good penetration capabilities, Depleted ura-nium alloys have already shined in armor-piercing projectiles. There should also be a lot of room for improvement in the application of fragment killing elements. Therefore, regarding the performance of the depleted uranium alloy to penetrate the target plate, further investigation is needed to analyze its advantages and disadvantages compared to tungsten alloy. To study the difference in penetration per-formance between depleted uranium alloy and tungsten alloy fragments,firstly, a theoretical analysis of the adiabatic shear sensitivity of DU and tungsten alloys was given from the perspective of material constitutive model. Then, taking the cylindrical fragment penetration target as the research object, the penetration process and velocity characteristics of the steel target plates penetrated by DU alloy frag-ment and tungsten alloy fragment were compared and analyzed, by using finite element software ANSYS/LS-DYNA and Lagrange algorithm. Lastly, the influence of different postures when impacting target and different fragment shapes on the penetration results is carried out in the research. The results show that in the penetration process of the DU and tungsten alloy fragments, the self-sharpening properties of the DU alloy can make the fragment head sharper and the penetrating ability enhance. Under the same conditions, the penetration capability of cylindrical fragment impacting target in vertical posture is better than that in horizontal posture, and the penetration capability of the spherical fragment is slightly better than that of cylindrical fragment.     

Effect of fusion welding processes on tensile properties of armor grade,high thickness,non-heat treatable aluminium alloy joints

AA5059 is one of the high strength armor grade aluminium alloy that finds its applications in the military vehicles due to the higher resistance against the armor piercing (AP) threats. This study aimed at finding the best suitable process among the fusion welding processes such as gas tungsten arc welding (GTAW) and gas metal arc welding (GMAW) by evaluating the tensile properties of AA5059 aluminium alloy joints. The fracture path was identified by mapping the low hardness distribution profile (LHDP) across the weld cross section under tensile loading. Optical and scanning electron microscopies were used to characterize the microstructural features of the welded joints at various zones. It is evident from the results that GTAW joints showed superior tensile properties compared to GMAW joints and this is primarily owing to the presence of finer grains in the weld metal zone (WMZ) and narrow heat-affected zone (HAZ). The lower heat input associated with the GTAW process effectively reduced the size of the WMZ and HAZ compared to GMAW process. Lower heat input of GTAW process results in faster cooling rate which hinders the grain growth and reduces the evaporation of magnesium in weld metal compared to GMAW joints. The fracture surface of GTAW joint consists of more dimples than GMAW joints which is an indication that the GTAW joint possess improved ductility than GMAW joint.     

热塑性互穿聚合物网络研究综述

概述了热塑性互穿聚合物网络（ＴＩＰＮ）的研究进展及其结构特点、制各方法和熔体的流动性,并对ＴＩＰＮ的前景作了简要的分析。